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Stan’s Legacy

Leak resistance across a tubular cell

Through what resistance does the charge on this tube leak away, given the water's conductivity?

The formula
R=ln(b/a)2π·σ·l
R
Leak resistance, Ω
a
Inner diameter, in
b
Outer diameter, in
l
Length, in
σ
Conductivity, µS/cm
LaTeX
R = \frac{\ln(b / a)}{2\pi \cdot σ \cdot l}

Work it out

in

The inner electrode's outside diameter.

in

The outer electrode's inside diameter.

in

The overlapping length of the two tubes.

µS/cm

What a conductivity meter reads. Distilled is 1–5 µS/cm; tap water 200–800; sea water about 50 000.

Method

  1. Convert the conductivity to siemens per metre (1 µS/cm is 10⁻⁴ S/m) and the length to metres.
  2. The resistance between coaxial cylinders through a conducting medium is ln(b/a) ÷ (2πσl) — the same logarithm as the capacitance, inverted, because the current spreads through the same annulus the field does.
  3. Divide by the length in inches for the per-inch figure.

Assumptions

  • The water's conductivity is what the meter says and is uniform. Under a high field it is not: ions crowd the electrodes, gas forms at them, and the effective resistance during a pulse differs from the meter reading, usually upward.
  • DC resistance. At the pulse frequency the water's loss is partly dielectric, which the Cole-Cole calculation covers; this is the ionic conduction alone.
  • No electrode effects. The electrochemical double layer at each tube adds a series capacitance and a polarisation resistance that this ignores.